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Update 13 May 2014

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Drinking water
Ion exchange processes

Introduction

Ion exchange is not a general method to treat drinking water. The production of potable water is usually done with other techniques: coagulation, filtration, disinfection and, when desalting sea water, reverse osmosis. Nevertheless, ion exchange can be very helpful to remove selectively targeted contaminants.

Contaminants

The table below shows the contaminants that can be removed with ion exchange, and some that must be removed with other processes.
 

Contaminant Comments Ion exchange removal
Hardness There is no prescribed limit for hardness in drinking water. Softening is more a question of comfort. The process is a normal softening, using special resins agreed for the treatment of drinking water.
Nitrate Nitrate is not a problem for adults, but it is harmful for infants. The recommended level is less than 50 mg/L. Nitrate can be removed with special, selective resins.
Perchlorate Perchlorate contaminates some water wells close to production sites of rocket fuels. The recommended level is less than 6 µg/L in California. Perchlorate can be removed with special, selective anion exchange resins. Resins used for nitrate removal are also effective for perchlorate.
Boron Boric acid is present in sea water RO permeate. The recommended level is 5 mg/L. Boron can be removed with special, selective resins.
Lead Excessive Pb levels may be due to old lead pipes. Lead can be removed with carboxylic (WAC) resins. Softeners also remove Pb.
Barium Barium is a component of hardness, and forms insoluble salts. The recommended WHO limit is 0.7 mg/L. Sulphonic (SAC) resins have a high selectivity for barium.
Chromate The presence of chromate in underground water is mostly due to industrial pollution. The recommended limit for Cr(VI) is 50 µg/L. Special WBA resins can be used to remove chromate from water.
Radium Radium is a component of hardness, but it has natural radioactivity. The American EPA has set a limit for a maximum combined value of 5 pCi/L (0.185 Bq/L). Ra is found in trace amounts in uranium ores. Radium can be removed with sulphonic (SAC) resins.
Uranium The toxicity of uranium is not due to its radioactivity, it is purely chemical. The WHO guideline is 15 µg/L. Uranium(VI) is present in nature as the uranyl ion UO2++ and can be removed with WBA or SBA resins.
Other heavy metals Heavy metals may be present in underground water, either naturally or due to pollution. Many metals can be removed with chelating resins, but those are not authorised in all countries.
Arsenic As is found in some natural water sources. The recommended limit is 10 µg/L. There is no proven ion exchange process to remove arsenic selectively. Other media, such as granulated iron hydroxide or titanium oxide, can be used.
Fluoride Ground water is sometimes contaminated with fluoride originating from industrial waste, e.g. aluminium mills. The recommended WHO limit for the F anion is 1.5 mg/L. Anion resins have a low selectivity for fluoride, so that selective removal is not practical. The usual process involves activated alumina.

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