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29 Dec 2013

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Ion exchange resin properties

Introduction

Macroporous resinWe will examine the meaning of

and examples will be shown.

The structure (matrix and functional groups) of ion exchange resins is described in other pages, as well as details of total and operating ion exchange capacity.

The importance of ionic form

In expressing the results of most resin properties, the ionic form should always be mentioned, as the values are different according to the ions in the resin beads. This applies in particular to the following properties:

and to a lesser extent to the particle size. For example, Amberjet 4400 has a total capacity of about 1.5 eq/L in the Cl form and 1.2 eq/L in the OH form. The difference is just due to resin swelling: it swells by up to 30 % between the Cl and the OH form. The number of active groups in a resin sample is obviously constant, so that when the resin swells, the density of these active groups decreases, and the volume capacity is a measure of this active groups density.

Example: analysis of a batch of new resin

Resin type Amberlite IRA96
Lot number 6210AA55
Volume capacity [free base form] 1.36 eq/L
Dry weight capacity [free base] 5.16 eq/kg
Dry matter [free base] 264 g/L
Strongly basic capacity 8.6 %
Moisture holding capacity [free base] 61.8 %
Perfect beads 98 %
Whole beads 99 %
Specific gravity [free base] 1.04
Particle size
Mean diameter 0.68 mm
Uniformity coefficient 1.34
Harmonic mean size 0.67 mm
Effective size 0.53 mm
Fines through 0.300 mm 0.1 %
Coarse beads on 1.18 mm 0.2 %
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Particle size distribution

Traditionally, the particle size distribution of a resin was measured using a set of sieves. The volume on the resin fraction remaining on each sieve is measured in a glass cylinder. It was found practical to express the results in cumulative percentage through a given sieve opening.

Today, granulometry is measured with particle counters which are linked to a computer and calculate all particle size parameters. The components of a particle size distribution are:

Amberjet 1200
Uniform resin
UC = 1.07
IR120
Conventional resin
UC = 1.60
We will review each of these properties.
Measuring particle size
Bell curve Example of traditional analysis measuring the volume of resin retained on each sieve:

mm % retained on sieve % through sieve
1.25 0.8 99.2
1.00 2.0 97.2
0.80 14.9 82.3
0.63 33.2 49.1
0.50 32.5 16.6
0.40 14.1 2.5
0.315 2.0 0.5
Finer 0.5  

The values "between sieves" have been plotted on a graph with a logarithmic scale for the sieve openings. In theory, and very roughly in practice as well, the particle size distribution of conventional "kettle polymerised" resins is normal, or Gaussian. A Gaussian bell curve has been superimposed on the graph.

Definitions
Gaussian-logarithmic representationUsing a Gaussian-logarithmic paper, a normal distribution (cumulated percentage through the sieves) will appear as a straight line, as shown on the picture here. In the past, this paper was used to calculate mean diameter, effective size and uniformity coefficient based on the laboratory results. This example displays the results corresponding to the bell curve above. The points are not exactly aligned due to imprecision in the sieving, and due to the fact that the actual distribution is not exactly Gaussian. The characteristic values for this example are:

Mean (median) diameter0.640 mm
Uniformity coefficient1.53
Effective size0.449 mm
Harmonic mean size0.616 mm

For resins wiith uniform particle size, the median diameter, harmonic mean size and effective size are close to each other. They would be identiical for resins totally uniform, i.e. with a uniformity coefficient equal to 1.00. See the bell curve and the Gaussian-logarithmic plot for a resin with uniformity coefficient 1.10.

What particle size means
Fine resin Coarse resin

Bead size is important

The choice of particle size is a compromise: fine resins deliver a higher capacity, but cause high head loss, and excess fines may produce nozzle clogging. Coarse beads on the other hand are frequently more sensitive to osmotic stress and have slower kinetics, thus giving a lower operating capacity. For all applications requiring separation of different resins in the same column, such as stratified or mixed bed units, selection of the right particle size is of critical importance.
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Ion exchange capacity

Total capacity Both volume and dry weight capacity values must be reported.

Operating capacity

Total capacities of new resins are measured for quality control. Capacities are expressed in equivalents per litre of wet resin or in equivalents per kilogramme of dried resin. The dry weight capacity indicates if a resin has been properly functionalised, irrespective of its water content. Whilst a high total capacity is generally desirable, not all exchange sites are used in a complete ion exchange cycle. Details on the concept of total and operating capacity are presented in another page.

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Moisture holding capacity

Moisture (water retention, or water content) is related to porosity and ionic form. The water content is expressed as a percentage of the moist resin weight in a given ionic form. Here is the influence of porosity on resin performance:

High moisture

Low moisture

About half the weight of all ion exchange resins is water, unless they have been dried or the water has been replaced with an organic solvent. The water surrounds the active groups (hydration water) and fills the voids in the resin matrix. Obviously, a resin with high moisture has less dry matter, therefore less active groups and less capacity; but on the other hand, such a resin may provide easier access for large ions into its structure.

For gel resins, the amount of water is inversely related to the degree of crosslinking of the matrix. This is not true for macroporous resins, because their (artificial) macroporosity can be varied as a parameter independent from crosslinking. See the "resin structure" page.

Usually, low moisture resins have a slower exchange rate and are more susceptible to fouling than high moisture resins.

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Dry matter

The dry matter is calculated: *The dry matter in kg/L is numerically equal to the volume capacity (in eq/L) divided by the dry weight capacity (in eq/kg).

The dry matter was used in the past by some manufacturers instead of the percentage of moisture retention. Today, the dry matter concept is not much used any more.

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Specific gravity (true bead density)

Density is important for

Although not an item for routine testing, specific gravity is an important parameter for successful plant operation. It is critical for all processes involving mixing or separation of 2 or 3 resins in the same column, and for adjustment of resin backwash flow rate.
Measurement of the specific gravity is made with a pycnometre.

Note that specific gravity varies with the ionic form of the resin. The ionic composition of a resin varies all the time during a cycle, so it is difficult to predict the exact specific gravity. This is important to understand when backwashing a resin bed.

Here are some typical values:

Specific gravity vs ionic form
Resin type Ionic form Density range Typical
WAC H 1.16 to 1.19 1.18
WAC Ca 1.28 to 1.34 1.32
SAC H 1.18 to 1.22 1.20
SAC Na 1.26 to 1.32 1.28
SAC Ca 1.28 to 1.33 1.31
WBA Free base 1.02 to 1.05 1.04
WBA Cl 1.05 to 1.09 1.06
WBA SO4 1.08 to 1.13 1.11
SBA OH 1.06 to 1.09 1.07
SBA Cl 1.07 to 1.10 1.08
SBA SO4 1.10 to 1.14 1.12
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Bulk density and shipping weight

The bulk density of a resin is usually expressed as the mass of one litre of the resin. As there are small variations of bulk density from batch to batch, a standard value, called shipping weight, is used for packaging the resin in the production plant. The variations of bulk density are mainly due to residual water in the bulk resin after removal of the interstitial water on the draining belt just before packaging.

Example :
Assume the bulk density values for a given resin type have a range of 720 to 780 g/L. Setting the shipping weight at 770 g/L will have the following results:

If the bulk density is at its maximum, the resin manufacturer is only undershipping a little, whilst if the density is lower than the shipping weight, he is overshipping some resin, so the customer will receive at least the ordered quantity in 83% of the cases. If the shipping weight had been set in the middle of the range, the customer would get less resin than ordered in 50% of the cases.
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Bed compression

Bed compression
The "missing resin" story: it is relatively difficult to measure bulk density values, as wall effects and bed compression are disturbing the measurement of bed depth and volume. The "100 %" point is for a small column with 50 mm diameter and 600 mm bed depth. With two metres bed depth (blue line) and one metre filter diameter, the bed is compressed by 2.5 %, giving the impression that 2.5 % of the resin is missing.

The picture here has been measured by a customer who was not sure if the delivered resin volume was correct.

 

 

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Optical aspect

Optical aspect
Optical aspect of a used resin
We look at the resin sample under the microscope. This test is the first done with used resins: if the sample is badly fragmented, resin replacement will be necessary so that further testing is not needed.

The optical aspect of a new resin, i.e. the number of cracked beads and fragments, is an important part of resin quality control in production. The quality control methods use the concept of perfect beads and whole beads. Perfect beads are just perfect, i.e. not cracked, not broken. Whole beads are spherical, i.e. not a fragment, but can be cracked.
For samples of used resins, the aspect can give valuable information about operating problems. So for instance in a used sample the following values are reported:

PBC (perfect bead count)65 %
WBC (whole bead count)94 %
This means that the sample has: Some people find this way to count not easy to understand. Just remember that whole beads comprise both perfect beads and cracked beads.

See pictures of new resin samples.

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Ionic form and volume change

Resins change volume according to the ions loaded on them. For instance, a gel type strongly basic resin may swell by more than 25 % if it is totally converted from the chloride form (as delivered) to the hydroxide form.

Here are the most usual ionic forms of delivery for resins used in water treatment, and an idea about their volume change.

Resin type Ionic form as supplied Total volume change From...To Example
SAC Na, H 6 to 10 % Na to H Amberjet 1000
SBA Cl, OH, SO4 15 to 30 %
6 to 10 %
Cl to OH
Cl to SO4
Amberjet 4200
WBA Free base (FB) 10 to 25 % FB to Cl Amberlite IRA96
WAC H 15 to 40 %
60 to 100 %
H to (Ca+Mg)
H to Na
Amberlite IRC86

More accurate data about resin swelling are usually available in the individual product data sheets pubilshed by the resin producers.

The volume change is due to the different hydration state of the ions in the resin: for instance, weak resins are almost not dissociated in regenerated form, so there are no free ions in the resin beads. Once they have exchanged ions, though, these ions are hydrated:

Ion hydration

Resins are rarely fully converted from 100 % regenerated to 100 % exhausted, so in general the maximum theoretical volume change is not achieved. However, a volume change does take place in operation, and is visible if you watch the resin bed surface in a column before and after regeneration. This is important in the case of packed beds where there is almost no freeboard.

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Stability

Resins must withstand various forms of stress in operation: The manufacturers offer specific resins according to operating conditions. Ask their experts.
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Ion exchange reactions

Chemical reactions of the ion exchange resins are shown in a dedicated page.
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Selectivity

The structure of resins and their selectivity for various ions are explained in separate pages.

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© François de Dardel
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